Thermodynamics of electrolytes. X. Enthalpy and the effect of temperature on the activity coefficients |
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| Authors: | Leonard F Silvester Kenneth S Pitzer |
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| Institution: | (1) Department of Chemistry and Lawrence Berkeley Laboratory, University of California, 94720 Berkeley, California |
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| Abstract: | Heat of dilution and of solution data are fitted to the form of equation corresponding to that used successfully for activity and osmotic coefficients over a wide range of concentrations. The resulting parameters give the change with temperature of the activity and osmotic coefficients. Results are reported for 84 electrolytes of 1-1, 2-1, 3-1, and 2-2 valence types. |
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| Keywords: | Enthalpy heat of dilution heat of solution activity coefficient electrolyte thermodynamics |
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