One-carbon extrusion from carbohydrates via C1-alkoxy radical fragmentation. An easy access to erythrose and threose |
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Authors: | Junji Inanaga Yuichi Sugimoto Yasuo Yokoyama and Takeshi Hanamoto |
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Institution: | Institute for Molecular Science, Myodaiji Okazaki 444 Japan |
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Abstract: | Generation and fragmentation of the C1-alkoxy radicals of pyranose derivatives are nicely promoted by (diacetoxyiodo)benzene or lead tetraacetate in the presence of iodine catalyst under mild conditions to give the corresponding mixed-acetal formates which are further converted to the furanose derivatives by acid-catalysed transacetalization. |
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