| C60/C70键联1,4-二-(咔唑-9-亚甲基)苯的电化学行为与双光子吸收 |
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| 引用本文： | 谭海荣,曾和平. C60/C70键联1,4-二-(咔唑-9-亚甲基)苯的电化学行为与双光子吸收[J]. 高等学校化学学报, 2009, 30(5): 934-937 |
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| 作者姓名： | 谭海荣 曾和平 |
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| 作者单位： | 华南理工大学化学与化工学院功能分子研究所,广州,510641 |
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| 基金项目： | 国家自然科学基金,广东省科技计划项目 |
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| 摘 要： | 设计合成了C60键联1,4-二-(咔唑-9-亚甲基)苯(5)和C70键联1,4-二-(咔唑-9-亚甲基)苯(6), 用红外、核磁共振和MALDI-TOF质谱进行了表征, 确认了化合物5和6的结构, 用循环伏安法研究了化合物5和6的电化学性质, 并用Z扫描对其双光子吸收性质进行了研究.
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| 关 键 词： | C60/C70键联1 4-二-(咔唑-9-亚甲基)苯 循环伏安 双光子吸收 |
| 收稿时间： | 2008-09-18 |
Electrochemistry Behavior and Two-photon Absorption Characteristic of C_(60)/C_(70) Bonded with 1,4-Bis[(carbazole-9-yl)methyl]benzene |
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| TAN Hai-Rong,ZENG He-Ping. Electrochemistry Behavior and Two-photon Absorption Characteristic of C_(60)/C_(70) Bonded with 1,4-Bis[(carbazole-9-yl)methyl]benzene[J]. Chemical Research In Chinese Universities, 2009, 30(5): 934-937 |
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| Authors: | TAN Hai-Rong ZENG He-Ping |
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| Affiliation: | Institute of Functional Molecule;School of Chemistry and Chemical Engineering South China University of Technology;Guangzhou 510641;China |
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| Abstract: | C60/C70 bonded with 1,4-bis[(carbazole-9-yl)methyl]benzene was synthesized and characterized by FTIR, 1H NMR and MALDI-TOF. Electrochemical properties of compounds 5 and 6 were studied by cyclic voltammetry. In the meanwhile, two-photon absorption cross-sector values(σTPA) of derivatives were also tested by open aperture Z scan experiment. |
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| Keywords: | 60/C70 bonded with 1,4-bis[(carbazole-9-yl) methyl]benzene')" href=" #" >C60/C70 bonded with 1,4-bis[(carbazole-9-yl) methyl]benzene Cyclic voltammograms Two-photon absorption |
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