Complexes of phosphorus halides with two or more coordination bonds |
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Authors: | L V Bezgubenko S E Pipko A D Sinitsa |
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Institution: | 1.Institute of Organic Chemistry,National Academy of Sciences of Ukraine,Kiev,Ukraine |
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Abstract: | The review considers complexes of phosphorus as central atom with the variously dentate ligands of different topology and
type of donor groups. The most stable complexes form the N-donor ligands, which are strong nucleophiles. The P-donor ligands
stabilize the lower oxidation state of phosphorus. Only a few examples of complexes is known of the neutral O- and S-donor
ligands. The most stable are the chelates with the ligands forming with the phosphorus atom alongside a donor-acceptor bond
also a common covalent bond. |
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