Solid state synthesis and crystal structure of a novel cluster, [WS4Ag3I(AsPh3)3](SAsPh3) |
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| Authors: | Genta Sakane Takashi Shibahara Hongwei Hou Yu Liu Xinquan Xin |
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| Affiliation: | (1) Department of Chemistry, Okayama University of Science, 1-1 Ridai-cho, 700 Okayama, Japan;(2) State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, 210093 Nanjing, P. R. China |
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| Abstract: | Summary The cluster [WS4Ag3I(AsPh3)3](SAsPh3) was prepared by the solid state reaction of (NH4)2WS4, AgI and AsPh3 at low heat. Some AsIII atoms were oxidized to Asv in the process. The structure of [WS4Ag3I(AsPh3)3](SAsPh3) was determined by single crystal X-ray diffractometry and can be described as the combination of cubane-like [WS4Ag3I(AsPh3)3] with an SAsPh3 moiety. |
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