Regio- and stereoselective synthesis of 1-aryl-1-thio-2-thiophosphinylethene derivatives via a radical process |
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| Authors: | Akinori Sato Koichiro Oshima |
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| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan |
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| Abstract: | Radical additions of S-thiophosphinyl dithiocarbonate to terminal aromatic alkynes afford (E)-1-aryl-1-thio-2-thiophosphinylethene derivatives regio- and stereoselectively in high yields. The transformations of the products are also described. |
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| Keywords: | Radical reaction C-P bond formation C-S bond formation Dithiocarbonate |
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