Mechanistic divergence of two closely related aldol-like enzyme-catalysed reactions |
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| Authors: | Ahn Meekyung Pietersma Amy L Schofield Linley R Parker Emily J |
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| Institution: | Institute of Fundamental Sciences, Massey University, Private Bag 11-222, Palmerston North, New Zealand. |
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| Abstract: | The analysis of the interaction of threose 4-phosphate and 2-deoxyerythrose 4-phosphate with 3-deoxy-D-arabino-heptulosonate 7-phosphate synthase (DAH7PS) reveals previously unrecognised mechanistic differences between the DAH7PS-catalysed reaction and that catalysed by the closely related enzyme, 3-deoxy-D-manno-octulosonate 8-phosphate synthase (KDO8PS). |
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