Synthesis of tetracarbocyanines by the scission of the pyrylium ring of benzopyrylocyanines |
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Authors: | A I Tolmachev V P Sribnaya I K Ushenko |
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Institution: | (1) Institute of Organic Chemistry As UkrSSR, Kiev |
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Abstract: | It has been shown that the reaction of monomethinecyanines containing 4-benzopyrylium residues with quaternary salts of derivatives of 2-(1 , 5 , 5 -trimethylcyclohex-1 -en-3 -ylidene)-methyl]benzothiazole leads to the scission of the pyrylium ring and the addition of the quaternary salt to the position of scission. The reaction gives tetracarbocyanines containing an o-hydroxyphenyl or an o-acetoxyphenyl substituent in the polymethine chain in addition to a hydrocarbon ring. |
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