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铁氧化物/金磁性核壳纳米粒子的制备及其富集与SERS研究
引用本文:鲍芳,姚建林,顾仁敖. 铁氧化物/金磁性核壳纳米粒子的制备及其富集与SERS研究[J]. 高等学校化学学报, 2008, 29(8): 1552-1554
作者姓名:鲍芳  姚建林  顾仁敖
作者单位:苏州大学化学系,苏州,215006;苏州大学化学系,苏州,215006;苏州大学化学系,苏州,215006
基金项目:国家自然科学基金,教育部高等学校博士学科点专项科研基金,江苏省自然科学基金,国家重点实验室基金
摘    要:本文用种子生长法制备铁氧化物/金磁性核壳纳米粒子, 并利用SERS对其磁场靶向性进行了检测.

关 键 词:磁性核壳纳米粒子  表面增强拉曼光谱  铁氧化物/金
收稿时间:2008-03-07

Preparation of Magnetic Fe Oxide Core/Au Shell Nanoparticles and Their Surface-enhanced Raman Spectroscopy
BAO Fang,YAO Jian-Lin,GU Ren-Ao. Preparation of Magnetic Fe Oxide Core/Au Shell Nanoparticles and Their Surface-enhanced Raman Spectroscopy[J]. Chemical Research In Chinese Universities, 2008, 29(8): 1552-1554
Authors:BAO Fang  YAO Jian-Lin  GU Ren-Ao
Affiliation:Department of Chemistry, Suzhou University, Suzhou 215006, China
Abstract:Fe oxide core/Au shell nanoparticles were prepared by the reduction of Au3 onto the surfaces of Fe oxide nanoparticles and characterized by scanning electron microscopy(SEM). The results reveal that the prepared core/shell nanoparticles were covered by Au shell and the surfaces of the core/shell particles are jagged after the initial addition of Au3 . Surface enhanced Raman scattering(SERS) activities of these magnetic nanoparticles were studied by using pyridine(Py) as a probe molecule after a magnet was used to concentrate the colloid. It was found that the SERS intensity depends on the Au shell thickness of the core/shell nanoparticles and strengthens with the increasing shell thickness. The detection limit for Py can be very low when the magnetic Fe oxide core/Au shell nanoparticles were used and even down to 10-7 mol/L.
Keywords:Magnetic core/shell nanoparticles  Surface enhanced Raman spectrum  Fe oxide/Au
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