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| 钾的N-酰化牛磺酸配合物的合成、表征及其晶体结构 | |
| 引用本文： | 兰翠玲,张淑华,蒋毅民. 钾的N-酰化牛磺酸配合物的合成、表征及其晶体结构[J]. 无机化学学报, 2005, 21(1): 87-90 |
| 作者姓名： | 兰翠玲 张淑华 蒋毅民 |
| 作者单位： | 1. 广西师范大学化学化工学院,桂林,541004;广西右江民族师范高等专科学校化学系,百色,533000 2. 桂林工学院材料与化学工程系,桂林,541004 3. 广西师范大学化学化工学院,桂林,541004 |
| 基金项目： | 广西科学基金项目(No:0339034)，广西高校科研基金项目资助 |
| 摘 要： | The title complex(K(C9H13NO5S2)(H2O)) was synthesized by the reaction of p-tolysulfonyl chloride, taurine and potassium hydrate in water-methanol-ethanol solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 336.44. The crystal structure of the title complex belongs to orthorhombic space group Pbca and cell parameters: a=0.853 31(12) nm, b=0.820 42(12) nm, c=3.989 4(6) nm. V=2.792 8(7) nm3, Z=8, Dc=1.600 g·cm-3, μ=0.699 mm-1, F(000)=1 400. The compound is an one-dimension chain complex of infinite length which are connected with hydrogen bond and bridging coordination water. The difference and same of the complexes were discussed. CCDC: 244938. |
| 关 键 词： | 配合物； N-酰化牛磺酸； 晶体结构 |
| 文章编号： | 1001-4861(2005)01-0087-04 |
| 收稿时间： | 2004-04-26 |
| 修稿时间： | 2004-04-26 |
Synthesis, Characterization and Crystal Structure of the Complexes of Potassium with N-Acidate Taurine |
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| LAN Cui-Ling,ZHANG Shu-Hua and JIANG Yi-Min. Synthesis, Characterization and Crystal Structure of the Complexes of Potassium with N-Acidate Taurine[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(1): 87-90 | |
| Authors: | LAN Cui-Ling ZHANG Shu-Hua JIANG Yi-Min |
| Affiliation: | College of Chemistry Chemical Engineering, Guangxi Normal University, GuiLin 541004;Department of Chemistry, Guangxi Youjiang Teachers College for Nationalities Baise 533000,Department of Material and Chemical-Engineering, GuiLin University of Technology, GuiLin 541004 and College of Chemistry Chemical Engineering, Guangxi Normal University, GuiLin 541004 |
| Abstract: | |
| Keywords: | complex N-acidate taurine crystal structure |
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