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3-N-苄氧羰基-β-氨基丁酸水杨酸酯类化合物的合成及其生物活性
引用本文:臧洪俊,李正名,倪长春,沈宙,范志金,刘秀峰.3-N-苄氧羰基-β-氨基丁酸水杨酸酯类化合物的合成及其生物活性[J].高等学校化学学报,2006,27(3):468-471.
作者姓名:臧洪俊  李正名  倪长春  沈宙  范志金  刘秀峰
作者单位:1. 天津工业大学材料科学与化学工程学院,天津,300160
2. 南开大学元素有机化学研究所,元素有机化学国家重点实验室,天津,300071
3. 国家南方农药创制中心上海基地,上海,200032
基金项目:国家自然科学基金重点项目(批准号:20432010),国家自然科学基金(批准号:30270883)资助.
摘    要:利用活性分子组合的原理,把两种具有诱导活性的水杨酸酯类化合物和D,L-β-氨基丁酸连接在一个分子内,合成了9个新化合物,所有新化合物经元素分析及1H NMR确认. 生物活性初步测定结果表明,该类化合物具有一定的诱导活性.

关 键 词:D  L-β-氨基丁酸  水杨酸酯  植物诱导抗性  生物活性
文章编号:0251-0790(2006)03-0468-04
收稿时间:01 19 2005 12:00AM
修稿时间:2005-01-19

Synthesis and Bioactivity of Salicylic Acid 3-N′-Benzyloxy-carbonyl-β-aminobutyric Ester
ZANG Hong-Jun,LI Zheng-Ming,NI Chang-Chun,SHEN Zhou,FAN Zhi-Jin,LIU Xiu-Feng.Synthesis and Bioactivity of Salicylic Acid 3-N′-Benzyloxy-carbonyl-β-aminobutyric Ester[J].Chemical Research In Chinese Universities,2006,27(3):468-471.
Authors:ZANG Hong-Jun  LI Zheng-Ming  NI Chang-Chun  SHEN Zhou  FAN Zhi-Jin  LIU Xiu-Feng
Institution:1. School of Material Science and Chemistry Engineering,Tianjin Polytechnic University,Tianjin 300160,China;
2. Research Institute of Elemento-organic Chemistry,State Key Labortary of Elemento-organic Chemisty,
Nankai University,Tianjin 300071,China;
3. Shanghai Branch of National Pesticide R &; D South Center,Shanghai 200032,China
Abstract:The plant activators such as salicylic acid and D,L-β-aminobutyric acid can induce systemic resiatance acquired in the treated plants against following pathogen attack. Utilizing coordination of active moieties,the chemical activators were designed to incorporate some structural moieties from β-aminobutyric and salicylic acid ester. Nine new compounds were prepared,whose structures were confirmed by elemental analysis and 1H NMR. The biocactivity of them was tested and the results indicate that several compounds show a certain induced activity against pathogen infection.
Keywords:β-Aminobutyric acid  Salicylic acid ester  Plant-induced resistance  Bioactivity
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