The influence of the nature of surfactants and dispersion medium on the catalytic effect of reverse micellar systems |
| |
Authors: | L. Ya. Zakharova A. R. Ibragimova F. G. Valeeva L. A. Kudryavtseva |
| |
Affiliation: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
| |
Abstract: | The catalytic effect of reverse micellar systems in alkaline hydrolysis of phosphonic acid esters is to a considerable extent determined by the structure of the substrate and surfactant and the nature of the oil phase but weakly depends on the surface potential of the aggregates. AOT-butanol-decane-water, sodium dodecyl sulfate-butanol-decane-water, and cetyltrimethylammonium bromide-butanol-decane-water microemulsions exhibit specific catalytic properties rather than catalytic properties intermediate between those of the surfactant-alkane-water and surfactant-alkanol-water three-component systems. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|