Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions |
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| Authors: | Carlson Bryan Aquino Adelia J A Hope-Weeks Louisa J Whittlesey Bruce McNerney Brian Hase William L Krempner Clemens |
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| Institution: | Department of Chemistry and Biochemistry, Texas Tech University, Memorial Dr & Boston, Lubbock, TX 79409, USA. |
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| Abstract: | The first zwitterionic alkaline earth metal silanides featuring two naked silyl anions were synthesized and a combined structural and computational study on these zwitterions revealed a correlation between the energy of the HOMO and the degree of negative charge of the naked silyl anions. |
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