When Cu4I4 cubane meets Cu3(pyrazolate)3 triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer |
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Authors: | Zhan Shun-Ze Li Mian Zhou Xiao-Ping Wang Jun-Hao Yang Ju-Rong Li Dan |
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Institution: | Department of Chemistry, Shantou University, Guangdong 515063, P. R. China. |
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Abstract: | A supramolecular dual emissive system incorporating two classical copper(I)-cluster-based luminophores, namely, Cu(4)I(4) and Cu(3)Pz(3) (Pz = pyrazolate), is reported. The targeted luminescent coordination polymer exhibits reversible thermochromism spanning from green to orange-red. |
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