Observation of micelle solution of decyltrimethylammonium bromide by electrospray ionization mass spectrometry |
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Authors: | Nohara D Bitoh M |
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Affiliation: | Faculty of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603, Japan. danohara@phar.nagoya-cu.ac.jp |
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Abstract: | A micelle solution of decyltrimethylammonium bromide (DTAB) was analyzed by electrospray ionization mass spectrometry. Finding an appropriate range of a capillary-skimmer potential was a prerequisite for obtaining a satisfactory spectrum. The mean molecular weight of DTAB aggregates, 10,500, was deduced from a series of mass spectra acquired at different capillary-skimmer potentials. The value was comparable with the micelle weight, previously determined by the light-scattering method. |
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