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| Crystal structure of a novel two-dimensional supramolecular network based on polyoxoanion and yttrium~Ⅲcoordination cation | |
| 作者姓名： | HE Shuiyang PENG Ke NING Wei WANG Daqi & SHI Qizhen Department of Chemistry Northwest University and Shaanxi Key Laboratory of Physico-Inorganic Chemistry Xi''''an 710069 China College of Chemistry and Chemical Engineering Liaocheng University Liaocheng 252059 China |
| 作者单位： | HE Shuiyang，PENG Ke，NING Wei，WANG Daqi & SHI Qizhen Department of Chemistry，Northwest University and Shaanxi Key Laboratory of Physico-Inorganic Chemistry，Xi'an 710069，China; College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng 252059，China |
| 摘 要： | A novel compound (NH4)2Y(H2O)8[PMo10V2O40]·10H2O has been prepared in an aqueous solution and characterized by elemental analysis, IR, and TG-DTG analysis. X-ray diffraction analysis was carried out on (NH4)2Y(H2O)8 [PMo10V2O40]·10H2O single crystal, which crystallizes in the monoclinic system of a space group P21/C with a=0.9871(3) nm,b=1.5424(5) nm,c=2.7924(9) nm,β=94.183(5)°and Z=2. In the compound, a two-dimensional network is constructed by the PMo10V2O405- anion and the Y(H2O)83 cation building blocks via hydrogen bonding exhibiting the porous structure. |
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