Stereoselective oxy-functionalization of gamma-silyl allylic alcohols with ozone: a facile synthesis of silyl peroxide and its reactions |
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| Authors: | Murakami Masanori Sakita Kyohei Igawa Kazunobu Tomooka Katsuhiko |
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| Institution: | Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan. |
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| Abstract: | A reaction of gamma-silyl allylic alcohol and its ether with ozone provides synthetically versatile alpha-formyl silyl peroxide in good yield without normal fission of carbon-carbon double bond. Thus, the provided silyl peroxide serves as a good precursor for the stereochemically defined triol derivative via alkylation and reduction of peroxide moiety. |
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