Homolytic cyclization of 1,3-propanedithiol to 1,2-dithiolane in the presence of 2,5-dimethyl-2,4-hexadiene |
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| Authors: | D V Demchuk G I Nikishin |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp, 117913 Moscow, Russian Federation |
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| Abstract: | 2,2-Diethyl-1,3-propanedithiol undergoes cyclization to 4,4-diethyl-1,2-dithiolane upon interaction with 2,5-dimethyl-2,4-hexadiene
in benzene in the presence of azodiisolbutyronitrile. The reaction proceeds according to the radical chain mechanism.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2078–2080, October, 1998. |
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| Keywords: | 2 2-diethyl-1 3-propanedithiol cyclization radical chain mechanism 4 4-diethyl-1 2-dithioaline |
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