Borrowing hydrogen: iridium-catalysed reactions for the formation of C-C bonds from alcohols |
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| Authors: | Black Phillip J Cami-Kobeci Gerta Edwards Michael G Slatford Paul A Whittlesey Michael K Williams Jonathan M J |
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| Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. |
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| Abstract: | Alcohols have been employed as substrates for C-C bond-forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner-Wadsworth-Emmons reaction, nitroaldol and aldol reactions. The 'borrowed hydrogen' is then returned to the alkene to form a C-C bond. |
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