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Novel donor-acceptor materials for organic light-emitting diodes based on α-cinnamoyl cyclic ketene dithioacetals
Authors:Ping Peng  Yixin Zhao  Haijian Xia  Qun Liu
Institution:a Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130023, China
b Department of Chemistry, Northeast Normal University, Changchun 130024, China
Abstract:A new family of α-cinnamoyl cyclic ketene dithioacetals (CCKDA) based on a typical donor-π-acceptor structure were designed and synthesized. These unsymmetrical π-conjugated molecules consisted of different electron-donating moiety and the same ketene dithioacetals acceptor. The introduction of different donor moieties changed energy level parameters of the molecules and allowed a fine tuning of their optical and electrical properties. It is promising to apply these compounds in organic light-emitting diodes (OLED) as light-emitting and electron-transporting materials.
Keywords:Donor-acceptor organic molecule  α-cinnamoyl cyclic ketene dithioacetals  Solvatochromism
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