Optical and crystal-field analysis of Er ion in Y2O3-P2O5 thin films |
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Authors: | Ramzi Maâ lej,M. Dammak,J.-L. Deschanvres |
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Affiliation: | a Laboratoire de Physique Appliquée, Groupe de Physique Théorique, Département de Physique, Faculté des Sciences de Sfax, 3018 Sfax, Tunisie b Laboratoire des Matériaux et du Génie Physique, ENSPG, B.P. 46, 38402 Saint-Martin-d’Hères, France |
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Abstract: | Luminescence spectra of erbium ions doped in Y2O3-P2O5 thin films, with different P2O5 content (from 3% to 47%), were analysed with crystal-field Hamiltonian model with D2d symmetry including J-mixing effect. The empirical crystal-field parameters (CFPs) obtained for the best fit of calculated to experimental energy levels allows us to confirm the well-established YPO4 phase for 47% of P2O5. The CFPs are compared to those calculated for Ce3+, Nd3+ and Dy3+ in the YPO4 host. This work is a continuation of our previous results for erbium-doped Y2O3 thin films. |
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Keywords: | 71.70.Ch |
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