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Stereospecific construction of contiguous quaternary and tertiary stereocenters by rearrangement from indoline-2-methanol to 2,2,3-trisubstituted tetrahydroquinoline: application to an efficient total synthesis of natural virantmycin
Authors:Ori Mayuko  Toda Narihiro  Takami Kazuko  Tago Keiko  Kogen Hiroshi
Institution:Exploratory Chemistry Research Laboratories, Sankyo Co., Ltd., 1-2-58 Hiromachi, Shinagawa-ku, Tokyo 140-8710, Japan.
Abstract:
Keywords:alkaloids  natural products  rearrangement  total synthesis
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