Syntheses,Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene |
| |
| Authors: | Rong-Yi Huang Guang-Xiang Liu Huan-Min Xu Sadafumi Nishihara Xiao-Ming Ren |
| |
| Affiliation: | (1) Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, People’s Republic of China;(2) Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan; |
| |
| Abstract: | Abstract Three new complexes, namely [Zn(mbix)(SO4)]·CH3OH (1), Cd(mbix)2(NO3)2 (2) and [Cd(mbix)2(H2O)2]·(NO3)2 (3), have been obtained by reactions of flexible bidentate ligand 1,3-bis(imidazol-1-ylmethyl)benzene (mbix) with corresponding zinc(II) and cadmium(II) salts. The structures of these complexes have been determined by the X-ray single crystal diffraction analysis. Complex 1 features a 2D wavy network with (4,4) topology. Complex 2 has a 2D grid network with left- and right-handed helical chains, while complex 3 exhibits twofold parallel interpenetration structure. The differences of three complexes demonstrate that the coordination geometry of metal ions and the ratio of reactants have a great impact on the structure of the supramolecular architectures. The luminescent properties of three complexes are also investigated. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
