Synthesis and structure of phenylbismuth bis(chloroacetate) |
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| Authors: | I. V. Egorova V. V. Sharutin T. K. Ivanenko N. A. Nikolaeva A. A. Molokov |
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| Affiliation: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia |
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| Abstract: | Crystals of phenylbismuth bis(chloroacetate) were synthesized by the reaction of triphenylbismuth with chloroacetic acid. Tridentate chelate-bridging chloroacetate ligands are bonded to neighboring molecules through the O atoms to form polymer chains. The Bi-O distances are equal to 2.36(1), 2.55(1), 2.78(1) and 2.30(1), 2.67(1), 2.85(2) Å. the length of the Bi-C bond is 2.26(2) Å. |
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