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Character of the thermal motion of water molecules according to the data on quasielastic incoherent scattering of slow neutrons
Authors:L. A. Bulavin  N. P. Malomuzh  K. N. Pankratov
Affiliation:(1) Shevchenko State University, Kiev, Ukraine;(2) Mechnikov State University, Odessa, Ukraine
Abstract:The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature.
Keywords:thermal molecule motion in water  incoherent neutron scattering  collective self-diffusion
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