{W48} ring opening: Fe16-containing, Ln4-stabilized 49-tungsto-8-phosphateopen wheel [Fe16O2(OH)23(H2O)9(P8W49O189)Ln4(H2O)20]11- |
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| Authors: | Ismail Amal H Bassil Bassem S Yassin Ghada H Keita Bineta Kortz Ulrich |
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| Affiliation: | Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen, Germany. |
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| Abstract: | Wheely: For the first time and very unexpectedly, a rupture of the very stable {P(8)W(48)} wheel was observed in aqueous solution at pH?4 and 80?°C in the presence of Fe(III), Eu(III)/Gd(III), and H(2)O(2). This inorganic ring opening is unprecedented in polyoxometalate chemistry. |
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