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Chemical modification of dispersed silica by pyrimidine derivatives
Authors:V. A. Basyuk  V. I. Bogomaz  A. A. Chuiko
Affiliation:(1) Surface Chemistry Department of the L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev
Abstract:Results are given of the chemical modification of silicas containing 
$$ - _/^backslash  Si - Cl,  - _/^backslash  Si - CH_2 Cl,$$
and 
$$ - _/^backslash  Si (CH_2 )_3 NH_2 $$
groups on their surface by pyridimidines in the gaseous phase. IR spectroscopy and field desorption mass spectrometric methods were used to obtain information on the structure of the surface compounds prepared. Possible reaction schemes are suggested. The high hydrolytic stability of some of the immobilized hydroxypyrimidines has been established.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 22, No. 4, pp. 495–499, July–August, 1986.
Keywords:
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