Oxidative properties of perfluoroalkyl halides |
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| Authors: | I N Rozhkov S M Igumnov G Ya Bekker S I Pletnev G D Rempel' L E Deev |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | On the basis of half-wave potential values E1/2 it was shown that perfluoroalkyl halides have pronounced oxidative properties in comparison with unfluorinated analogs. Tertiary perfluoroalkyl iodides, having a higher oxidation potential than iodine, react with I– by a scheme including one-electron transfer.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2222–2224, October, 1989. |
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