Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides |
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| Authors: | Sulway Scott A Layfield Richard A Tuna Floriana Wernsdorfer Wolfgang Winpenny Richard E P |
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| Affiliation: | School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. |
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| Abstract: | [Cp(2)Dy(thf)(μ-Cl)](2) (2) was synthesized from [Cp(2)Dy(μ-Cl)](n), which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased. |
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