Synthesis of an analogue of the marine polypropionate tridachiahydropyrone |
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Authors: | Jeffery David W Perkins Michael V White Jonathan M |
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Institution: | School of Chemistry, Physics and Earth Sciences, Flinders University, G. P. O. Box 2100, S.A. 5001, Australia. |
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Abstract: | reaction: see text] A novel approach to the formation of the unusual pyrone-containing ring systems as found in polypropionate metabolites from the Tridachia family of marine molluscs has been developed. This approach includes an intramolecular cyclization of a beta-keto acid onto a cyclohexenone ring to afford a fused, bicyclic pyrone. |
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