Hydrocarbon hydrogenolysis on nickel-tin catalysts |
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Authors: | V D Stytsenko I A Eigenson H Lausch S Engels and A Ya Rozovskii |
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Institution: | (1) Institute of Petrochemical Synthesis, 117912 Moscow, USSR;(2) Technische Hochschule, 4200 Leuna-Merseburg, GDR |
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Abstract: | Hydrogenolysis of ethane, n-hexane and cyclohexane has been studied on nickel-kieselguhr catalysts modified by organic and inorganic compounds of tin. Tin additives decrease nickel reactivity with respect to C–C dissociation, which is ascribed to the formation of surface intermetallides on the catalyst.
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