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Solid-state chelates of ethylenediamine- tetraacetate with alkali earth metals
Authors:A B S Moitinho  E Y Ionashiro  G R de Souza  F L Fertonani
Institution:(1) Instituto de Química, Universidade Estadual Paulista, Araraquara, Săo Paulo, C.P. 355, CEP 14.800-900, Brazil
Abstract:Solid-state M-EDTA chelates, where M represents the divalent ions Mg(II), Ca(II), Sr(II) or Ba(II) and EDTA is ethylenediaminetetraacetate anion, were synthesized. Thermogravimetry, derivative thermogravimetry (TG, DTG), differential scanning calorimetry (DSC) and X-ray diffraction powder patterns have been used to characterize and to study the thermal behaviour of these chelates. The results provided information concerning the stoichiometry, crystallinity, thermal stability and thermal decomposition. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:alkali earth metals  thermal behaviour  EDTA
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