PtCl(PHCy2)[(PCy2O)2H]: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex |
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| Authors: | Mastrorilli Piero Latronico Mario Nobile Cosimo Francesco Suranna Gian Paolo Fanizzi Francesco Paolo Englert Ulli Ciccarella Giuseppe |
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| Institution: | Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari, via Orabona 4, I-70125 Bari, Italy. p.mastrorilli@poliba.it |
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| Abstract: | Exposure of solid trans-Pt(PHCy2)2(PCy2)Cl] (1) to dry oxygen unexpectedly leads to PtCl(PHCy2)(PCy2O)2H]] (2) as the major product, the formation of which has been followed by NOESY 1H NMR techniques. |
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