Kinetics and mechanism of aniline hydroxylation by cumene hydroperoxide in the presence of catalase |
| |
Authors: | A A Akhrem S N Kiseleva and P A Kiselev |
| |
Institution: | (1) Institute of Bioorganic Chemistry, Minsk, USSR |
| |
Abstract: | In a phosphate buffer with pH=7.4 at 20°C the kinetics of aniline hydroxylation to p-aminophenol by the catalase-cumene hydroperoxide system has been studied. The reaction mechanism of this system is discussed.
![Pcy](/content/w37770g652312513/xxlarge1055.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) 20°C ![fcy](/content/w37770g652312513/xxlarge1092.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![fcy](/content/w37770g652312513/xxlarge1092.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![bcy](/content/w37770g652312513/xxlarge1073.gif) ![ucy](/content/w37770g652312513/xxlarge1091.gif) ![fcy](/content/w37770g652312513/xxlarge1092.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) pH 7,4 ![icy](/content/w37770g652312513/xxlarge1080.gif) ![zcy](/content/w37770g652312513/xxlarge1079.gif) ![ucy](/content/w37770g652312513/xxlarge1091.gif) ![chcy](/content/w37770g652312513/xxlarge1095.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![lcy](/content/w37770g652312513/xxlarge1083.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![lcy](/content/w37770g652312513/xxlarge1083.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![pcy](/content/w37770g652312513/xxlarge1087.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![fcy](/content/w37770g652312513/xxlarge1092.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![ldquo](/content/w37770g652312513/xxlarge8220.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![lcy](/content/w37770g652312513/xxlarge1083.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![zcy](/content/w37770g652312513/xxlarge1079.gif) -![gcy](/content/w37770g652312513/xxlarge1075.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![dcy](/content/w37770g652312513/xxlarge1076.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![pcy](/content/w37770g652312513/xxlarge1087.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![kcy](/content/w37770g652312513/xxlarge1082.gif) ![ucy](/content/w37770g652312513/xxlarge1091.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![lcy](/content/w37770g652312513/xxlarge1083.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) . ![Pcy](/content/w37770g652312513/xxlarge1055.gif) ![rcy](/content/w37770g652312513/xxlarge1088.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![vcy](/content/w37770g652312513/xxlarge1074.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![dcy](/content/w37770g652312513/xxlarge1076.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![ocy](/content/w37770g652312513/xxlarge1086.gif) ![bcy](/content/w37770g652312513/xxlarge1073.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![ucy](/content/w37770g652312513/xxlarge1091.gif) ![zhcy](/content/w37770g652312513/xxlarge1078.gif) ![dcy](/content/w37770g652312513/xxlarge1076.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![khcy](/content/w37770g652312513/xxlarge1093.gif) ![acy](/content/w37770g652312513/xxlarge1072.gif) ![ncy](/content/w37770g652312513/xxlarge1085.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![zcy](/content/w37770g652312513/xxlarge1079.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) ![dcy](/content/w37770g652312513/xxlarge1076.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![jcy](/content/w37770g652312513/xxlarge1081.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![vcy](/content/w37770g652312513/xxlarge1074.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![icy](/content/w37770g652312513/xxlarge1080.gif) ![scy](/content/w37770g652312513/xxlarge1089.gif) ![tcy](/content/w37770g652312513/xxlarge1090.gif) ![iecy](/content/w37770g652312513/xxlarge1077.gif) ![mcy](/content/w37770g652312513/xxlarge1084.gif) .
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |