Cocrystallization of two isomers of N′-(5-nitrofurfurylidene)benzhydrazide and features of the molecular,crystal, and electronic structure of their crystal hydrate |
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Authors: | S M Aldoshin O A Kozina G L Gutsev E G Atovmyan L O Atovmyan V S Nedzvetskii |
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Institution: | 1. Institute of Chemical Physics, Chernogolovka Branch, Academy of Sciences of the USSR, USSR
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Abstract: | 1. |
An x-ray diffraction structural study of crystals of N -(5-nitrofurfurylidene)benzhydrazide revealed the first case of the cocrystallization of syn and syn-anti isomers of ketohydrazone molecules. We propose that the isomerization of the ketohydrazone molecules occurs upon crystallization and is a consequence of packing effects. The crystal structure of this ketohydrazone is a rare case of the laminar packing of polar and nonpolar molecular chains.
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The formation of hydrates of N -(5-nitrofurfurylidene)hydrazides radically alters the structure of their frontier molecular orbitals in comparison with the anhydrous molecules. This may significantly affect the properties of the crystals of these compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2301–2308, October, 1988. |
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