Direct electrochemical synthesis of N-oxopyridine-2-thionato complexes of nickel(II), cobalt(II) and cobalt(III) |
| |
| Authors: | J. Sanmartín M. R. Bermejo J. A. García-Vázquez J. Romero A. Sousa J. Strähle A. Brodbeck |
| |
| Affiliation: | (1) Dpto. de Química Inorgánica, Universidad de Santiago de Compostela, E-15706 Santiago de Compostela, Spain;(2) Institut für Anorganische Chemie der Universität Tübingen, D-7400 Tübingen, Germany |
| |
| Abstract: | Summary The electrochemical oxidation of anodic metal (nickel or cobalt) in MeCN solutions of 1-hydroxy-2-pyridinethione (HPT) gives [Ni(PT)2], [Co(PT)2] or [Co(PT)3]. When 1,10-phenanthroline (phen) or 2,2 -bipyridine (bipy) are added to the electrolytic phase the product is a complex, [Ni(PT)2L] or [Co(PT)2L] (L = bipy or phen). The i.r., u.v. and 1H- and 13C-n.m.r. spectra of the complexes are discussed.This paper was presented at the 5th Inorganic Chemistry Meeting of the Royal Spanish Chemical Society, Tossa de Mar, Girona, Spain, September 1991. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
