Interaction of dimethyl sulphoxide with chloranil by ESR and optical methods |
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Authors: | A K Roy B K Sarkar S Sanyal |
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Institution: | (1) Saha Institute of Nuclear Physics, 700 009 Calcutta, India;(2) Bose Institute, 700 009 Calcutta, India |
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Abstract: | The molecular charge-transfer absorption bands have been observed in solution of dimethyl sulphoxide (DMSO) and tetrachloro-p-benzoquinone (chloranil) in chloroform and cyclohexanone. The stability constant, the thermodynamic parameter of the complex
and the extinction co-efficient of CT bands at 350 nm in chloroform and 360 nm in cylohexanone have been estimated on the
assumption of the 1:1 complex formation. Detection of ESR signal of the solution of chloranil in pure DMSO (g ≈ 2) indicates the formation of chloranil radical anion, the precursor being the charge-transfer complex, which dissociates
partly in high dielectric constant DMSO. |
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Keywords: | Charge transfer electron spin resonance optical property |
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