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Luminescence Monitoring of Lanthanide Catalysts for Diene Polymerization |
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| Authors: | Bulgakov R G Kuleshov S P Zuzlov A N Vafin R R Rusakov S V Mullagaliev I R Dzhemilev U M Monakov Yu B |
| Institution: | (1) Academy of Sciences of Bashkortostan, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Institute of Petrochemistry and Catalysis, 450075 Bashkortostan, Russia;(2) Ufa Scientific Center, Russian Academy of Sciences, Ufa, Institute of Organic Chemistry, 450054 Bashkortostan, Russia |
| Abstract: | Changes in the luminescence characteristics of Tb3+ and Ce3+ lanthanide ions in the interaction of LnCl3 · 3(BuO)3PO complexes with iso-Bu3Al in the absence and presence of piperylene were studied. As a result, a new luminescence approach was proposed to study reaction mechanisms in the synthesis of lanthanide catalysts for diene polymerization. |
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