Tertiary Acetylenic Alcohols and Diols on the Basis of Phenylacetylene and 2-Methyl-3-butyn-2-ol |
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Authors: | Potkin V I Dikusar E A Kozlov N G |
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Institution: | (1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, Minsk, 220072, Belarus |
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Abstract: | A procedure has been proposed for the synthesis of tertiary acetylenic alcohols and diols by treatment of phenylacetylene or 2-methyl-3-butyn-2-ol with butyllithium and subsequent reaction of lithium phenylacetylide or lithium 4-lithio-2-methyl-3-butyn-2-olate thus obtained with alicyclic, aromatic, and terpene ketones. |
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