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Tertiary Acetylenic Alcohols and Diols on the Basis of Phenylacetylene and 2-Methyl-3-butyn-2-ol
Authors:Potkin  V I  Dikusar  E A  Kozlov  N G
Institution:(1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, Minsk, 220072, Belarus
Abstract:A procedure has been proposed for the synthesis of tertiary acetylenic alcohols and diols by treatment of phenylacetylene or 2-methyl-3-butyn-2-ol with butyllithium and subsequent reaction of lithium phenylacetylide or lithium 4-lithio-2-methyl-3-butyn-2-olate thus obtained with alicyclic, aromatic, and terpene ketones.
Keywords:
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