| 尾式金属卟啉配合物的研究：Ⅸ.苯丙氨酸基尾式卟啉及其锌 … |
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| 引用本文： | 刘海洋,陈瑞耘.尾式金属卟啉配合物的研究：Ⅸ.苯丙氨酸基尾式卟啉及其锌 …[J].光谱学与光谱分析,1999,19(2):151-153. |
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| 作者姓名： | 刘海洋 陈瑞耘 |
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| 作者单位： | [1]中山大学化学系 [2]中山大学分析测试中心 |
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| 基金项目： | 国家自然科学基金,马灿安教育基金 |
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| 摘 要： | 本文合成了Ｌ－苯丙氨酸基尾式卟啉及其锌配合，研究了它们的荧光性质，观察到苯丙所酸卟啉环之间在激发态分子内能量转移过程，讨论了影响卟啉特征荧光峰位置的配位化学因素。
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| 关 键 词： | 卟啉锌 锌 配合物 苯丙氨酸基 尾式卟啉 荧光 |
Studies on tailed metalloporphyrin coordination compounds. IX. Synthesis of tailed porphyrin with covalently linked phenylalanine and its fluorescence property] |
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| Haiyang LIU,Jinwang HUANG,Hengyi LEI,Chunlian ZENG,Liangnian JI.Studies on tailed metalloporphyrin coordination compounds. IX. Synthesis of tailed porphyrin with covalently linked phenylalanine and its fluorescence property][J].Spectroscopy and Spectral Analysis,1999,19(2):151-153. |
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| Authors: | Haiyang LIU Jinwang HUANG Hengyi LEI Chunlian ZENG Liangnian JI |
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| Institution: | Department of Chemistry, Zhongshan University, 510275 Guangzhou. |
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| Abstract: | A new tailed porphyrin with covalently linked phenylalanine 2 and its zinc complex 3 were synthesized.Intramolecular energy transfer (from singlet excited phenylalanine to porphyrin)was observed in compound 2 and 3.The influence of coordination chemistry factor on the fluorescence of porphyrin was also discussed. |
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| Keywords: | Phenylalanine porphyrin Fluorescence Intramolecular energy transfer |
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