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| Formation of Oligosaccharide from Monosaccharide by Pentacoordinate Oxyphosphorane | |
| 摘 要： | PhosphorusphalymanybioChemicalreactions['j,suchasthereactionsofADPandAtw].H....ersofarlndeisknownaboathowthePhoSPhruspeesPartintheformationofoligosaccharides.Duhatheinvesigallonofthereaedonofglucose(l)wAnOxyPhosPhorane(2),weisolatedtheproduCtwhosemolecularweighwasverifiedbytheFAB-MS.ItwasAnownthatwhenglycosidesweremixedwAnAnmetalinns,OulytheadductionsofmoleculewAnalkalimetalionsaPPearedinthehighmassregionlcyAforeddinganaPPrOPateaznountofNa+ormp+tothefinalProdCtS,StrOngadduCtinn… |
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