Original TDAE strategy using α-halocarbonyl derivatives |
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Authors: | Marc Since |
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Institution: | Laboratoire de Pharmaco-Chimie Radicalaire LPCR, UMR CNRS 6264, Université de la Méditerranée, Faculté de Pharmacie, 27 Boulevard Jean Moulin, 13385 Marseille Cedex 05, France |
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Abstract: | We report herein the selective C-C bond formation by the reaction of nitrobenzyl carbanions, formed via the TDAE strategy, with α-haloesters and α-haloamides. This reaction, extended in benzodioxole and dimethoxybenzene series provides new potentially CNS active agents. |
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