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Tetrathiafulvalenyl-acetylacetonate complexes of difluoroboron
Authors:Michel Guerro
Affiliation:Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Campus de Beaulieu, Bât 10A, 35042 Rennes cedex, France
Abstract:A series of tetrathiafulvalene (TTF) derivatives functionalized by one or two β-diketonatoboron difluoride groups were synthesized through the addition of borontrifluoride to TTF substituted by one or two acetylacetone functions. The influence of the β-diketonatoboron difluoride moiety on the redox properties of the TTF has been investigated by cyclic voltammetry.
Keywords:Tetrathiafulvalene   β-Diketonate ligand   Boron difluoride   Redox behaviour
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