Light-fluorous TEMPO: reagent, spin trap and stable free radical |
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| Authors: | Adrian P. Dobbs Peter Jones Stephen E. Rigby |
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| Affiliation: | a School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London E1 4NS, UK
b Discovery Chemistry, Pfizer Global R&D, Sandwich, Kent CT13 9NJ, UK |
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| Abstract: | The synthesis of two light-fluorous TEMPO derivatives is reported, along with their fluorous-organic solvent partition coefficients and their ESR spectra. Applications of the fluorous-TEMPO reagents in oxidation reactions and as radical traps are discussed. |
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| Keywords: | Fluorous-TEMPO Fluorous solid-phase extraction ESR spectra Oxidation reaction Radical spin trap |
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