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Reactions of 2-(4-hydroxyanilino)-1,4-naphthoquinones with cerium ammonium nitrate and pyridinium chlorochromate
Authors:A E Devyashina  L M Gornostaev  Yu V Gatilov
Institution:1.Astaf’ev Krasnoyarsk State Pedagogical University,Krasnoyarsk,Russia;2.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division,Russian Academy of Sciences,Novosibirsk,Russia
Abstract:Reactions of 2-(4-hydroxyarylamino)-1,4-naphthoquinones with cerium ammonium nitrate or pyridinium chlorochromate depending on the structure of initial substrate and the type of reagent led to the formation of 2-chloro-3-(4-cyclohexa-2,5-dienylideneamino)-1,4-dihydronaphthalene-1,4-diones, 2-(4-hydroxy-3-nitrophenylamino)-1,4-naphthaquinones, and also to simultaneous oxidation and chlorination.
Keywords:
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