Synthesis of highly stable unusual charge-separated pyridinium-, isoquinolinium-, quinolinium-, and N-methylimidazolium-tetronic acid zwitterions |
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Authors: | Ahmad Shaabani Ali Hossein Rezayan Marjan Heidary |
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Affiliation: | a Department of Chemistry, Shahid Beheshti University, PO Box 19396-4716, Tehran, Iran b Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia |
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Abstract: | A unique strategy for the synthesis of highly stable unusual charge-separated pyridinium-, isoquinolinium-, quinolinium-, and N-methylimidazolium-tetronic acid zwitterions from the reaction of pyridine, isoquinoline, quinoline, and N-methylimidazole with dialkyl acetylenedicarboxylates and 3-chlorotetronic acid in EtOH at room temperature is described. |
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Keywords: | Tetronic acid zwitterions Ylides Pyridine 3-Chlorotetronic acid |
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