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电感耦合等离子体发射光谱法定量测试明胶中的微量金属元素Hg和Rh--应用MSF模型改进Hg结果的精密度和检测限
引用本文:杜保安,杨玉华,李正平.电感耦合等离子体发射光谱法定量测试明胶中的微量金属元素Hg和Rh--应用MSF模型改进Hg结果的精密度和检测限[J].光谱学与光谱分析,2006,26(1):140-143.
作者姓名:杜保安  杨玉华  李正平
作者单位:河北大学化学与环境科学学院,河北,保定,071002;华北电力大学应用数学系,河北,保定,071003
基金项目:中国科学院资助项目 , 河北省基础科研项目
摘    要:应用电感耦合等离子体发射光谱技术,建立了定量测试明胶中微量金属元素Hg和Rh的方法。采用湿法消解对明胶样品进行前处理。讨论了ICP-AES同时测定明胶中微量金属元素Hg和Rh时,应用MSF模型校正对汞的光谱干扰和背景干扰,改善了检测结果的精密度和检测限。实验结果表明,建立的方法准确、快速、高效、线性范围宽,得到的分析结果令人满意。

关 键 词:电感耦合等离子体发射光谱法(ICP-AES)  明胶  微量金属元素  MSF模型
文章编号:1000-0593(2006)01-0140-04
收稿时间:2004-08-08
修稿时间:2004-11-28

Determination of Trace Elements Hg and Rh in Gelatin by Inductively Coupled Plasma Emission Spectrometry--Applying MSF Model to Improve the Precision and Detection Limit
DU Bao-an,YANG Yu-hua,LI Zheng-ping.Determination of Trace Elements Hg and Rh in Gelatin by Inductively Coupled Plasma Emission Spectrometry--Applying MSF Model to Improve the Precision and Detection Limit[J].Spectroscopy and Spectral Analysis,2006,26(1):140-143.
Authors:DU Bao-an  YANG Yu-hua  LI Zheng-ping
Institution:1. Chemistry and Environment Science Institute of Hebei University, Baoding 071002, China2. Applied Mathematic Department, Electric Power University of North China, Baoding 071003, China
Abstract:Using ICP-AES, the method was developed to quantitatively determine the trace elements Hg and Rh in gelatin for the first time. The unknown samplers were processed with the wet digestion method. Multiple trace elements in gelatin could be quantitatively determined by ICP-AES at the same time. Applying the MSF model, the method to correct the spectral interference and the background was discussed. The result's precision and detection limit could be greatly improved by MSF model. The results of the experiment showed that the method features high accuracy, rapidity, high performance and a wide linear dynamic range, and the results were very satisfactory.
Keywords:Inductively coupled plasma atomic emission spectrometry (ICP-AES)  Gelatin  Trace element  MSF model
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