| 对酞内酰胺苯磺酰氯与胺类化合物的衍生反应 |
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| 引用本文： | 崔同,傅承光.对酞内酰胺苯磺酰氯与胺类化合物的衍生反应[J].应用化学,1996,13(5):97-99. |
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| 作者姓名： | 崔同 傅承光 |
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| 作者单位： | 河北农业大学食品科学系，河北大学理化分析研究中心 |
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| 摘 要： | 对酞内酰胺苯磺酰氯与胺类化合物的衍生反应崔同傅承光（河北农业大学食品科学系保定０７１００１）（河北大学理化分析研究中心保定）关键词对酞内酰胺苯磺酰氯，胺类化合物，衍生试剂，衍生反应对酞内酰胺苯磺酰氯（简称Ｐｈｉｓｙｌ－Ｃｌ）是一种新型高灵敏度荧光（紫...
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| 关 键 词： | 对酞内酰胺苯磺酰氯，胺类化合物，衍生试剂，衍生反应 |
| 收稿时间： | 1995-12-25 |
Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride |
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| Cui Tong.Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride[J].Chinese Journal of Applied Chemistry,1996,13(5):97-99. |
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| Authors: | Cui Tong |
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| Abstract: | The kinetic study showed that the water content has an important effect on the hydrolysis rate of phthalimidyl benzene sulphonyl chloride(Phisyl-Cl). The PH of the reaction medium should be higher than 8. 0 and 9. 0 for derivatization with primary and secondary amines respectively. The hydrolysis of PhisyI-Cl is inhibited by adding solid NaHCO_3 instead of its saturated solution to the medium to promote derivatization. |
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| Keywords: | phthalimidylbenzene sulphonyl chloride amine derivatizing reagent derivatization |
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