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聚苯醚磺酸锂与酯类增塑剂共混物的导电性
引用本文:汪传清,黄玉惠.聚苯醚磺酸锂与酯类增塑剂共混物的导电性[J].应用化学,1996,13(2):82-84.
作者姓名:汪传清  黄玉惠
作者单位:中国科学院广州化学研究所
基金项目:国家自然科学基金,国家科委国家基础性研究重大关键项目
摘    要:聚苯醚磺酸锂与酯类增塑剂共混物的导电性汪传清,黄玉惠,赵树录,丛广民(中国科学院广州化学研究所广州510650)关键词 聚苯醚磺酸锂,酯类增塑剂,共混,导电性能高分子固体电解质[1]可作为高能电池、电致变色等材料。聚环氧乙烷/碱金属盐复合物与无机盐构...

关 键 词:聚苯醚磺酸锂,酯类增塑剂,共混,导电性能
收稿时间:1995-06-19

Conductivity of the Blend of Sulfonated Poly(phenylene oxide) Lithium-Ester Plasticizers
Wang Chuanqing, Huang Yuhui, Zhao Shulu, Cong Guangmin.Conductivity of the Blend of Sulfonated Poly(phenylene oxide) Lithium-Ester Plasticizers[J].Chinese Journal of Applied Chemistry,1996,13(2):82-84.
Authors:Wang Chuanqing  Huang Yuhui  Zhao Shulu  Cong Guangmin
Abstract:In the present paper sulfonated poly (phenylene oxide)lithium (SPPOLi) was blended with ester plasticizers propylene carbonate, dioctyl phosphite, and butyl stearate, respectively.It was found that the dielectiric constants of plasticizers had a significant influence on the conductivity of blends: the plasticizer with high dielectric constant could increase the conductivity of SPPOLi effectively. It was also found that the dependence of the conductivity of blends on temperature was not consistent with the Arrhenius equation. The ionic migration numbers indicated that the blends were single-ion conductivity materials. X-ray diffraction was used to investigate the condensed state structure of the blends.
Keywords:sulfonated poly(phenylene oxide) lithium  ester plasticizer  blend  conductivity
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