Synthesis and molecular structure of [CpRu(1,4,7-S3C6H12)]O3SCF3 |
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Authors: | Mark Green M. Draganjac Yanjing Jiang A.W. Cordes |
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Affiliation: | (1) Department of Chemistry and Biochemistry, Arkansas State University, State University, Arkansas, 72467;(2) Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas, 72701 |
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Abstract: | The isolation and characterization of [CpRu(9S3)](O3SCF3), where 9S3 = 1,4,7-trithiacyclononane, is reported. The title compound crystallizes in the orthorhombic space group Pbca: a = 10.2542(18), b = 14.8991(13), c = 22.4832(18) Å, and Z = 8. The Ru atom is sandwiched between the -bound cyclopentadienyl ligand and the 9S3 ligand, bonding to all three of the sulfur atoms in the 9S3. The Ru—S distances are 2.2991(10), 2.2979(11), and 2.3055(10) Å. The C—S distances range from 1.819(4) to 1.852(5) Å in the trithiacyclononane ring. |
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Keywords: | Ruthenium 1,4,7-trithiacyclononane sandwich complex |
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